Physical and thermal properties of l‐lactide/ϵ‐caprolactone copolymers: the role of microstructural design

Understanding the underlying role of microstructural design in polymers allows for the manipulation and control of properties for a wide range of specific applications. As such, this work focuses on the study of microstructure–property relationships in l‐ lactide/?‐caprolactone (LL/CL) copolymers. One‐step and two‐step bulk ring‐opening polymerization (ROP) procedures were employed to synthesize LL/CL copolymers of various compositions and chain microstructures. In the one‐step procedure, LL and CL were simultaneously copolymerized to yield P(LL‐stat‐CL) statistical copolymers. In the two‐step procedure, poly(l‐ lactide) (PLL) and poly(?‐caprolactone) (PCL) prepolymers were synthesized in the first step before CL and LL respectively were added in the second step to yield P[LL‐b‐(CL‐stat‐LL)‐b‐LL] and P[CL‐b‐(LL‐stat‐CL)‐b‐CL] block copolymers as the final products. The findings reveal that, in addition to the copolymerization procedure employed, the length and type of the prepolymer play important roles in determining the chain microstructure and thereby the overall properties of the final copolymer. Moreover, control over the degree of crystallinity and the type of crystalline domains, which is controlled during the polymer chemistry process, heavily influences the physical and mechanical properties of the final polymer. In summary, this work describes an interesting approach to the microstructural design of biodegradable copolymers of LL and CL for potential use in biomedical applications. © 2019 Society of Chemical Industry     

印尼BAYAH电厂一次风机故障原因分析与处理

本文针对印尼BAYAH电厂一次风机设备故障，详细的分析了故障产生的原因，介绍了三点法找转子动平衡和工装车削式在线修复电机滑环工法，阐述了两种工法的原理以及实施步骤。     

高精度多环片自动装配控制技术

为了实现对微小环片零件的自动化装配,搭建了自动装配系统.通过4根直线导向轴与4个直线轴承来提高系统的导向精度和刚度.采用直线导轨进行各装配作业模块之间的切换,保证了微小环片零件的自动装配与取出.在环片的装配方向上,螺旋升降机和光栅尺实现环片的位置精度控制.在Lab VIEW编程环境中,采用分层软件架构和模块化控制思想,避免了不必要的数据循环检测与丢失,能够达到环片组件的装配精度要求.控制系统分为系统初始化模块、参数设置模块、装配模块和取出模块,自动装配系统通过各个模块间的相互交流配合完成装配任务.采用本文中自动装配系统装配环片的实验结果表明,环片零件装配的最大位置误差为26μm,垂直度误差为17μm,平均装配时间为75 s/片,可满足环片组件所需的精度要求.     

磁环表面缺陷图像分割算法的研究及实时实现

为实现小型磁环表面细微缺陷图像无监督分割,并提高分割精度与计算效率,本文提出了一种基于改进2D Gabor滤波器组的自适应阈值分割方法。首先,利用多尺度、多方向的Gabor滤波器组对缺陷图像进行滤波降噪处理,抑制目标区域与背景区域内部的噪声污染,同时增强区域间的差异性；然后,通过对处理后图像的灰度统计特性分析,根据缺陷图像的灰度均值及方差构造了灰度阈值计算公式,实现了小型磁环表面细微缺陷图像的自适应分割。实验结果表明,本文算法可快速、准确地分割缺陷并抑制噪声干扰,在分割精度、计算效率等方面也优于传统的选择迭代法、OTSU、最大熵等方法,并能够在先进的SEED-DVS8168平台上实时实现,验证了此算法的可行性与实时性。     

内燃机活塞环表面处理技术

活塞环在内燃机中有着支撑、密闭、储油、导热的作用,内燃机活塞环制备材料应该具备优良的加工性能、耐高温、耐腐蚀、导热性好且具有良好的强韧性,较好的与气缸材料表面的磨合性能。球墨铸铁和专用钢材已经成为制备内燃机活塞环的基础材料,目前国内外采用多种表面处理技术比如:镀铬、氮化、PVD与CVD镀膜、喷钼、喷涂陶瓷层等表面处理工艺进行表面改性,提高内燃机活塞环的使用寿命和使用性能。需要不断研究和开发新的内燃机活塞环的表面处理技术来满足实际生产和应用中内燃机越来越高的要求。     

Annular‐ring slot antenna designs with circular polarization radiation

The design of a microstrip‐fed annular‐ring slot antenna (ARSA) with circular polarization (CP) radiation is initially studied. To obtain CP radiation with broad 3‐dB axial ratio (AR) bandwidth that can cover the WiMAX 2.3 GHz (2305–2320 MHz, 2345–2360 MHz) and WLAN 2.4 GHz (2400–2480 MHz) bands, a novel technique of extending an inverted L‐shaped slot from the bottom section of the annular‐ring is proposed. To suppress the harmonic modes induced by the CP ARSA, the technique of integrating a defected ground structure into the annular‐ring slot is further introduced. From the measured results, 10‐dB impedance bandwidth and 3‐dB AR bandwidth of 44.86 and 9.68% were achieved by the proposed harmonic suppressed CP ARSA. Furthermore, average gain and radiation efficiency of ～4.7 dBic and 71%, respectively, were also exhibited across the bands of interest. © 2014 Wiley Periodicals, Inc. Int J RF and Microwave CAE 25:337–345, 2015.     

Green touch for hydrogen production via alkaline electrolysis: The semi-flexible PV panels mounted wind turbine design,production and performance analysis

The novel solar-wind integrated system has been firstly used for hydrogen production in literature with validating theoretical, simulated and experimental studies. This integrated system consists of two main parts; solar-assisted wind turbine and alkaline electrolysis cell.In the first part of this system, the semi-flexible PV panels are smoothly integrated on the vertical axis wind turbine blade. This is a unique design in literature, unlike the hybrid systems that include wind turbines and solar PV panels in published literature. The production and testing of the hybrid integrated system in a single structure were performed both in laboratory conditions and also the system was set up the roof of ATU (Adana Alparslan Turkes Science and Technology University) in Adana. The second part includes hydrogen production via alkaline electrolysis system. The cathodes consist of nickel-coated copper (Cu/Ni) and nickel-vanadium binary coated copper (Cu/NiV), that was produced via electrodeposition technique by self-supporting. The performance of electrodes was compared in 1 M KOH solution via I–V behavior, electrochemical impedance spectroscopy, and long term cathodic polarization analysis. Results showed that polarization resistance was decreased almost 4 times by NiV when comparing the Ni. The surface inhomogeneity values were 0.91 and 0.81 for Cu/Ni and Cu/NiV respectively. The hydrogen gas evolved at the cathodes was also measured and higher volumes were detected for NiV binary coating.     

18CrNiMo7-6环类锻件中白点缺陷的超声检测研究

将超声检测结果和缺陷波形特点进行分类和总结,并通过酸浸检验和断口检验对缺陷性质做出定性判断,验证了超声检测波形特征和白点缺陷的关联性,为通过超声检测手段来监控产品中是否存在白点缺陷提供参考。     

不同镍含量钨基碳化态催化剂对十氢萘加氢开环的影响

采用共浸渍法制备不同镍含量的Ni-W/ USY-Al2O3碳化态催化剂。通过N2吸附-脱附、元素分析、CO滴定、X射线衍射（XRD）、程序升温还原等技术对催化剂进行表征。以十氢萘为模型化合物考察了不同Ni含量钨基碳化态催化剂对十氢萘加氢开环反应性能的影响。结果表明，适当的镍钨原子比能够提高催化剂的金属活性位，进而提高催化剂的加氢开环性能。